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Nickel Oxide as an Electrode Material for Supercapacitors

Kui LIANG , Ai CHEN , Li HE , Wei WANG

材料科学技术(英)

The preparation of Ni oxide films and their capacitive mechanism are discussed in this paper. Nickel oxide film electrodes perform pseudocapacitance in aqueous KOH and NaOH but perform double layer capacitance in LiClO4/PC (propylence carbonate). The effect of increasing the specific capacitance was observed when Ni oxide film electrodes are doped with Co. A specific capacitance of around 70 F/g was achieved when using Ni oxide films doped with Co as electrodes and 1 mol/L aqueous KOH or NaOH as an electrolyte.

关键词: Supercapacitor , null , null , null

Nickel Oxide/Carbon Nanotubes Nanocomposite for Electrochemical Capacitance

Kui LIANG

材料科学技术(英)

A nanocomposite of nickel oxide/carbon nanotubes was prepared through a simple chemical precipitation followed by thermal annealing. The electrochemical capacitance of this electrode material was studied. When the mass fraction of CNTs (carbon nanotubes) in NiO/CNT composites increases, the electrical resistivity of nanocomposites decreases and becomes similar to that of pure CNTs when it reaches 30%. The specific surface area of composites increases with increasing CNT mass fraction and the specific capacitance reaches 160 F/g under 10 mA/g discharge current density at CNT mass fraction of 10%.

关键词: Nickel oxide , null , null , null

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